Phase Analysis Studies on Niobium Oxide Fluorides.
نویسندگان
چکیده
منابع مشابه
In Situ Vibrational Spectroscopy Studies of Supported Niobium Oxide Catalysts
The IR spectra of bulk Nb2O5‚nH2O and niobia supported on SiO2, Al2O3, ZrO2, and TiO2 were recorded in the fundamental and overtone NbdO regions, as well as in the hydroxyl region, to develop a better understanding of the structural models of surface NbOx species. The coincidence of the IR and Raman fundamental NbdO frequency in Nb2O5/Al2O3, Nb2O5/ZrO2, and Nb2O5/TiO2 provides the strongest evi...
متن کاملXAFS study of niobium oxide on alumina
The structure of the niobium oxide on alumina surface was investigated for low loading (5 wt.-%) and high loading (19 wt.-%) samples. The TPD profile of water molecules showed the appearance of water adsorption sites other than those on alumina. The XANES and EXAFS spectra clearly showed that niobic acid-like species are formed on the surface of 19 wt.-% NbO,/Al,O,. The XANES spectra of 5 wt.-%...
متن کاملMolecular Design of Supported Niobium Oxide Catalysts
The current investigation demonstrates that it is possible to molecularly design supported niobium oxide catalysts with the assistance of molecular characterization methods such as Raman spectroscopy. The formation and location of the surface niobium oxide species are controlled by the surface hydroxyl chemistry, and the surface niobium oxide species are located in the outermost layer of the ca...
متن کاملEELS investigations of different niobium oxide phases.
Electron energy loss spectra in conjunction with near-edge fine structures of purely stoichiometric niobium monoxide (NbO) and niobium pentoxide (Nb2O5) reference materials were recorded. The structures of the niobium oxide reference materials were checked by selected area electron diffraction to ensure a proper assignment of the fine structures. NbO and Nb2O5 show clearly different energy loss...
متن کاملPhase Transformation Studies of Metal Oxide Nanowires
Here, we report that the postsynthesis nitridation of tungsten oxide nanowires can result in single crystal nitride nanowires when the initial diameters of the nanowires are less than 10 nm. For nanowires with diameters greater than 10 nm, the nitridation of nanowires resulted in polycrystalline but highly oriented tungsten nitride domains in nanowires. Partially nitrided nanowires show an epit...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1964
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.18-2233